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| 1 |
ID:
093502
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| Publication |
2010.
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| Summary/Abstract |
Methanol production from biomass is a promising carbon neutral fuel, well suited for use in fuel cell vehicles (FCVs), as transportation fuel and as chemical building block. The concept used in this study incorporates an innovative Absorption Enhanced Reforming (AER) gasification process, which enables an efficient conversion of biomass into a hydrogen-rich gas (syngas) and then, uses the Mitsubishi methanol converter (superconverter) for methanol synthesis. Technical and economic prospects for production of methanol have been evaluated. The methanol plants described have a biomass input between 10 and 2000 MWth. The economy of the methanol production plants is very dependent on the production capacity and large-scale facilities are required to benefit from economies of scale. However, large-scale plants are likely to have higher transportation costs per unit biomass transported as a result of longer transportation distances. Analyses show that lower unit investment costs accompanying increased production scale outweighs the cost for transporting larger quantities of biomass. The unit cost of methanol production mostly depends on the capital investments. The total unit cost of methanol is found to decrease from about 10.66 R/l for a 10 MWth to about 6.44 R/l for a 60 MWth and 3.95 R/l for a 400 MWth methanol plant. The unit costs stabilise (a near flat profile was observed) for plant sizes between 400 and 2000 MWth, but the unit cost do however continue to decrease to about 2.89 R/l for a 2000 MWth plant. Long term cost reduction mainly resides in technological learning and large-scale production. Therefore, technology development towards large-scale technology that takes into account sustainable biomass production could be a better choice due to economic reasons.
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| 2 |
ID:
132631
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2014.
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| Summary/Abstract |
Municipal solid waste (MSW) collection and disposal is a major urban environment issue in the world today. MSW management solutions have to be technologically feasible, legally and socially acceptable and environmentally and financially sustainable. European policy is pushing for a rational management of natural resources; a promising technological perspective today is waste valorisation, a process that involves sorting at the source, combined with material recycling and waste-to-energy conversion. In this paper, we analyze the evolution of the Portuguese MSW management system, criticize the environmental policy issues for MSW management in Portugal and identify weak points in the criteria used for the technologies selection. Portugal is facing multiple problems with MSW management and is attempting to tackle them by passing legislation in order to improve the performance of waste management systems. At the technological level, gasification increasingly presents as an efficient and viable alternative to incineration. Gasification is a waste-to-energy conversion scheme that offers an attractive solution to both waste disposal and energy problems. Waste gasification by plasma has been validated but the economic viability of this technology must be proven before to be accepted by the industry.
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| 3 |
ID:
111399
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2012.
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| Summary/Abstract |
Biochar is a carbon- and energy-rich porous material produced through slow pyrolysis of biomass, which has been proposed as a way of storing carbon in soils for the long-term (centurial to millennial timescales) but its production incurs an energy penalty. Gasification of rice husks at paddy mills combines the benefits of reasonably efficient delivery of energy with a reasonably high carbon char and ash mixture. The ca. 35% carbon content of the rice husk char is possibly a consequence of the protective shield of silica, preventing full exposure of the biomass to oxidation in the gasifier. In this paper we undertake an evaluation of the sustainability of this 'gasification-biochar system' (GBS) in Cambodia, where a rapid deployment of gasifiers is underway. In Part I, we describe the context and analyse (some of) the physical and chemical properties of the biochar. While there are some potential health, safety and environmental issues that require further analysis, they are problems that could be readily addressed in further research and appear to be resolvable. In Part II, we present results from field trials, summarise the data on the carbon abatement of the gasification-biochar system and present some preliminary economic data.
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